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Civil Services Mains exam syllabus: Economic

Economic Syllabus for IAS Main Examination 2014

Paper-I

1. Advanced Micro Economics:

a.  Marshallian and Walrasiam Approaches to Price determination.
b.  Alternative Distribution Theories: Ricardo, Kaldor, Kaleeki
c.  Markets Structure : Monopolistic Competition, Duopoly, Oligopoly.
d.  Modern Welfare Criteria: Pareto Hicks & Scitovsky, Arrow’s Impossibility Theorem, A.K. Sen’s Social

2. Advanced Macro Economics:

Approaches to Employment Income and Interest Rate determination: Classical, Keynes (IS-LM) curve, Neo classical synthesis and New classical, Theories of Interest Rate determination and Interest Rate Structure

3. Money – Banking and Finance:

a.  Demand for and Supply of Money: Money Multiplier Quantity Theory of Money (Fisher, Pique and Friedman) and Keyne’s Theory on Demand for Money, Goals and Instruments of Monetary Management in Closed and Open Economies. Relation between the Central Bank and the Treasury. Proposal for ceiling on growth rate of money.

b.  Public Finance and its Role in Market Economy: In stabilization of supply, allocation of resources and in distribution and development. Sources of Govt. revenue, forms of Taxes and Subsidies, their incidence and effects. Limits to taxation, loans, crowding-out effects and limits to borrowings. Public Expenditure and its effects.

4. International Economics:
(a) Old and New Theories of International Trade

i.  Comparative Advantage
ii.  Terms of Trade and Offer Curve.
iii.  Product Cycle and Strategic Trade Theories.
iv.  Trade as an engine of growth and theories of under development in an open economy.

(b) Forms of Protection: Tariff and quota.

(c) Balance of Payments Adjustments:
Alternative Approaches.

i.  Price versus income, income adjustments under fixed exchange rates,
ii.  Theories of Policy Mix
iii.  Exchange rate adjustments under capital mobility
iv.  Floating Rates and their Implications for Developing Countries: Currency Boards.
v.  Trade Policy and Developing Countries.
vi.  BOP, adjustments and Policy Coordination in open economy macro-model.
vii.  Speculative attacks
viii.  Trade Blocks and Monetary Unions.
ix.  WTO: TRIMS, TRIPS, Domestic Measures, Different Rounds of WTO talks.

5. Growth and Development:
a.

  1. Theories of growth: Harrod’s model,
  2. Lewis model of development with surplus labour
  3. Balanced and Unbalanced growth,
  4. Human Capital and Economic Growth.
  5. Research and Development and Economic Growth

b.   Process of Economic Development of Less developed countries: Myrdal and Kuzments on economic development and structural change: Role of Agriculture in Economic Development of less developed countries.
c.   Economic development and International Trade and Investment, Role of Multinationals.
d.   Planning and Economic Development: changing role of Markets and Planning, Private- Public Partnership.
e.   Welfare indicators and measures of growth – Human Development Indices. The basic needs approach.
f.   Development and Environmental Sustainability – Renewable and Non Renewable Resources, Environmental Degradation, Intergenerational equity development.

Paper-II

1. Indian Economy in Pre-Independence Era:
Land System and its changes, Commercialization of agriculture, Drain theory, Laissez faire theory and critique. Manufacture and Transport: Jute, Cotton, Railways, Money and Credit.

2. Indian Economy after Independence:
A. The Pre Liberalization Era:

i.   Contribution of Vakil, Gadgil and V.K.R.V. Rao.
ii.  Agriculture: Land Reforms and land tenure system, Green Revolution and capital formation in agriculture,
iii.  Industry Trends in composition and growth, Role of public and private sector, Small scale and cottage industries.
iv.  National and Per capita income: patterns, trends, aggregate and Sectoral composition and changes their in.
v.  Broad factors determining National Income and distribution,Measures of poverty, Trends in poverty and inequality.

B. The Post Liberalization Era:

i.   New Economic Reform and Agriculture: Agriculture and WTO, Food processing, Subsidies, Agricultural prices and public distribution system, Impact of public expenditure on agricultural growth.
ii.  New Economic Policy and Industry: Strategy of industrialization, Privatization, Disinvestments,Role of foreign direct investment and multinationals.
iii.   New Economic Policy and Trade: Intellectual property rights: Implications of TRIPS, TRIMS, GATS and new EXIM policy.
iv.   New Exchange Rate Regime:Partial and full convertibility, Capital account convertibility.
v.   New Economic Policy and Public Finance: Fiscal Responsibility Act, Twelfth Finance Commission and Fiscal Federalism and Fiscal Consolidation.
vi.   New Economic Policy and Monetary system. Role of RBI under the new regime.
vii.   Planning: From central Planning to indicative planning, Relation between planning and markets for growth and decentralized   planning: 73rd and 74th Constitutional amendments.
viii.   New Economic Policy and Employment: Employment and poverty, Rural wages, Employment Generation, Poverty alleviation schemes, New Rural, Employment Guarantee Scheme

Civil Services Mains exam syllabus: Commerce and Accountancy

Commerce and Accountancy Syllabus for IAS Main Examination 2014

PAPER – I

Accounting and Finance Accounting, Taxation & Auditing

1. Financial Accounting :
Accounting as a Financial Information System; Impact of Behavioural Sciences. Accounting Standards e.g., Accounting for Depreciation, Inventories, Research and Development Costs, Long-term Construction Contracts, Revenue Recognition, Fixed Assets, Contingencies, Foreign Exchange Transactions, Investments and Government Grants, Cash Flow Statement, Earnings Per Share. Accounting for Share Capital Transactions including Bonus Shares, Right Shares, Employees Stock Option and Buy- Back of Securities.
Preparation and Presentation of CompanyFinal Accounts.
Amalgamation, Absorption and Reconstruction of Companies.

2. Cost Accounting :
Nature and Functions of Cost Accounting. Installation of Cost Accounting System. Cost Concepts related to Income Measurement, Profit Planning, Cost Control and Decision Making.

Methods of Costing: Job Costing, Process Costing, Activity Based Costing. Volume – cost – Profit Relationship as a tool of Profit Planning.

Incremental Analysis/ Differential Costing as a Tool of Pricing Decisions, Product Decisions, Make or Buy Decisions, ShutDown Decisions etc. Techniques of Cost Control and Cost Reduction: Budgeting as a Tool of Planning and Control. Standard Costing and Variance Analysis. Responsibility Accounting and Divisional Performance Measurement.

3. Taxation :
Income Tax: Definitions; Basis of Charge; Incomes which do not form Part of Total Income. Simple problems of Computation of Income (of Individuals only) under Various Heads, i.e., Salaries, Income from House Property, Profits and Gains from Business or Profession, Capital Gains, Income from other sources, Income of other Persons included in Assessee’s Total Income .
Set – Off and Carry Forward of Loss.Deductions from Gross Total Income.
Salient Features/Provisions Related to VAT and Services Tax.

4. Auditing :
Company Audit: Audit related to Divisible Profits, Dividends, Special investigations, Tax audit. Audit of Banking, Insurance, Non-Profit Organizations and Charitable Societies/ Trusts/Organizations.

Financial Management, Financial Institutions and Markets

1. Financial Management :
Finance Function: Nature, Scope and Objectives of Financial Management: Risk and Return Relationship.

Tools of Financial Analysis: Ratio Analysis, Funds-Flow and Cash-Flow Statement.Capital Budgeting Decisions: Process, Procedures and Appraisal Methods. Risk and Uncertainty Analysis and Methods.

Cost of capital: Concept, Computation of Specific Costs and Weighted Average Cost of Capital. CAPM as a Tool of Determining Cost of Equity Capital.

Financing Decisions: Theories of Capital Structure – Net Income (NI) Approach, Net Operating Income (NOI) Approach, MM Approach and Traditional Approach. Designing of Capital structure: Types of Leverages (Operating, Financial and Combined) EBIT- EPS Analysis, and other Factors.

Dividend Decisions and Valuation of Firm: Wal ter ’s Model , MM Thesis, Gordan’s Model Lintner’s Model. Factors Affecting Dividend Policy.Working Capital Management: Planning of Working Capital. Determinants of Working Capital. Components of Working Capital – Cash, Inventory and Receivables. Corporate Restructuring with focus on Mergers and Acquisitions (Financial aspects only)

2. Financial Markets and Institutions :
Indian Financial System: An Overview Money Markets: Participants, Structure and Instruments. Commercial Banks. Reforms in Banking sector. Monetary and Credit Policy of RBI. RBI as a Regulator.

Capital Market: Primary and Secondary Market. Financial Market Instruments and Innovative Debt Instruments; SEBI as a Regulator.

Financial Services: Mutual Funds, Venture Capital, Credit Rating Agencies, Insurance and IRDA.

PAPER – II

Organisation Theory and Behaviour, Human Resource Management and Industrial Relations

Organisation Theory and Behaviour

1. Organisation Theory :
Nature and Concept of Organisation; External Environment of Organizations -Technological, Social, Political, Economical and Legal; Organizational Goals – Primary and Secondary goals, Single and Mul t iple Goals; Management by Objectives.

Evolution of Organisation Theory: Classical, Neo-classical and Systems Approach. Modern Concepts of Organisation Theory:Organisat ional Design, Organisat ional Structure and Organisational Culture.

Organisational Design–Basic Challenges; Differentiation and Integration Process; Centralization and Decentralization Process; Standardization / Formalization and Mutual Adjustment. Coordinating Formal and Informal Organizations. Mechanistic and Organic Structures

Designing Organizational structures–Authority and Control; Line and Staff Functions, Specialization and Coordination. Types of Organization Structure –Functional. Matrix Structure, Project Structure. Nature and Basis of Power , Sources of Power, Power Structure and Politics. Impact of Information Technology on Organizational Design and Structure. Managing Organizational Culture

2. Organisation Behaviour:
Meaning and Concept; Individual in organizations: Personality, Theories, and Determinants; Perception – Meaning and Process.

Motivation: Concepts, Theories and Applications. Leadership-Theories and Styles. Quality of Work Life (QWL): Meaning and its impact on Performance, Ways of its Enhancement. Quality Circles (QC) – Meaning and their Importance. Management of Conflicts in Organizations. Transactional Analysis, Organizational Effectiveness, Management of Change.

Human Resources Management and Industrial Relations

1.Human Resources Management(HRM):
Meaning, Nature and Scope of HRM, Human Resource Planning, Job Analysis, Job Description, Job Specification, Recruitment Process, Selection Process, Orientation and Placement, Training and Development Process, Performance Appraisal and 360° Feed Back, Salary and Wage Administration, Job Evaluation, Employee Welfare, Promotions, Transfers and Separations.

2. Industrial Relations (IR):
Meaning, Nature, Importance and Scope of IR, Formation of Trade Unions, Trade Union Legislation, Trade Union Movement. in India. Recognition of Trade Unions, Problems of Trade Unions in India. Impact of Liberalization on Trade Union Movement. Nature of Industrial Disputes : Strikes and Lockouts , Causes of Disputes, Prevention and Settlement of Disputes.
Worker’s Participation in Management: Philosophy, Rationale, Present Day Status and Future Prospects.
Adjudication and Collective Bargaining.
Industrial Relations in Public Enterprises, Absenteeism and Labour Turnover in Indian Industries and their Causes and Remedies. ILO and its Functions.

Civil Services Mains exam syllabus: Civil Engineering

Civil Engineering Syllabus for IAS Main Examination 2014

Paper-I

 

1. Engineering Mechanics, Strength of Materials and Structural Analysis:

1.1 Engineering Mechanics:

Units and Dimensions, SI Units, Vectors, Concept of Force, Concept of particle and rigid body. Concurrent, Non Concurrent and parallel forces in a plane, moment of force, free body diagram, conditions of equilibrium, Principle of virtual work, equivalent force system.

First and Second Moment of area, Mass moment of Inertia.

Static Friction.

Kinematics and Kinetics:

Kinematics in Cartesian Co-ordinates, motion under uniform and nonuniform acceleration, motion under gravity. Kinetics of particle: Momentum and Energy principles, collision of elastic bodies, rotation of rigid bodies.

1.2 Strength of Materials:

Simple Stress and Strain, Elastic constants, axially loaded compression members, Shear force and bending moment, theory of simple bending, Shear Stress distribution across cross sections, Beams of uniform strength.

Deflection of beams: Macaulay’s method, Mohr’s Moment area method, Conjugate beam method, unit load method. Torsion of Shafts, Elastic stability of columns, Euler’s Rankine’s and Secant formulae.

1.3 Structural Analysis:

Castiglianio’s theorems I and II, unit load method of consistent deformation applied to beams and pin jointed trusses. Slope-deflection, moment distribution,

Rolling loads and Influences lines: Influences lines for Shear Force and Bending moment at a section of beam. Criteria for maximum shear force and bending Moment in beams traversed by a system of moving loads. Influences lines for simply supported plane pin jointed trusses.

Arches: Three hinged, two hinged and fixed arches, rib shortening and temperature effects.

Matrix methods of analysis: Force method and displacement method of analysis of indeterminate beams and rigid frames.

Plastic Analysis of beams and frames: Theory of plastic bending, plastic analysis, statical method, Mechanism method.

Unsymmetrical bending: Moment of inertia, product of inertia, position of Neutral Axis and Principle axes, calculation of bending stresses.

2. Design of Structures: Steel, Concrete and Masonry Structures:

2.1 Structural Steel Design:

Structural Steel: Factors of safety and load factors. Riveted, bolted and welded joints and connections. Design of tension and compression member, beams of built up section, riveted and welded plate girders, gantry girders, stancheons with battens and lacings.

2.2 Design of Concrete and Masonry Structures:

Concept of mix design. Reinforced Concrete: Working Stress and Limit State method of design–Recommendations of I.S. codes Design of one way and two way slabs, stair-case slabs, simple and continuous beams of rectangular, T and L sections. Compression members under direct load with or without eccentricity,

Cantilever and Counter fort type retaining walls.

Water tanks: Design requirements for Rectangular and circular tanks resting on ground.

Prestressed concrete: Methods and systems of prestressing, anchorages, Analysis and design of sections for flexure based on working stress, loss of prestress.

Design of brick masonry as per I.S. Codes

3. Fluid Mechanics, Open Channel Flow and Hydraulic Machines:

3.1 Fluid Mechanics:

Fluid properties and their role in fluid motion, fluid statics including forces acting on plane and curved surfaces.

Kinematics and Dynamics of Fluid flow: Velocity and accelerations, stream lines, equation of continuity, irrotational and rotational flow, velocity potential and stream functions.

Continuity, momentum and energy equation, Navier-Stokes equation, Euler’s equation of motion, application to fluid flow problems, pipe flow, sluice gates, weirs.

3.2 Dimensional Analysis and Similitude:

Buckingham’s Pi-theorem, dimensionless parameters.

3.3 Laminar Flow:

Laminar flow between parallel, stationary and moving plates, flow through tube.

3.4 Boundary layer: Laminar and turbulent boundary layer on a flat plate, laminar sub layer, smooth and rough boundaries, drag and lift. Turbulent flow through pipes: Characteristics of turbulent flow, velocity distribution and variation of pipe friction factor, hydraulic grade line and total energy line.

3.5 Open channel flow:

Uniform and non-uniform flows, momentum and energy correction factors, specific energy and specific force, critical depth, rapidly varied flow, hydraulic jump, gradually varied flow, classification of surface profiles, control section, step method of integration of varied flow equation.

3.6 Hydraulic Machines and Hydropower:

Hydraulic turbines, types classification, Choice of turbines, performance parameters, controls, characteristics, specific speed. Principles of hydropower development.

4. Geotechnical Engineering:

Soil Type and structure – gradation and particle size distribution – consistency limits.

Water in soil – capillary and structural – effective stress and pore water pressure – permeability concept – field and laboratory determination of permeability – Seepage pressure – quick sand conditions – Shear strength determination – Mohr Coulomb concept.

Compaction of soil – Laboratory and field tests.

Compressibility and consolidation concept – consolidation theory – consolidation settlement analysis.

Earth pressure theory and analysis for retaining walls, Application for sheet piles and Braced excavation.

Bearing capacity of soil – approaches for analysis – Field tests – settlement analysis – stability of slope of earth walk.

Subsurface exploration of soils – methods

Foundation – Type and selection criteria for foundation of structures – Design criteria for foundation – Analysis of distribution of stress for footings and pile – pile group action-pile load test. Ground improvement techniques.

Paper-II

1. Construction Technology, Equipment, Planning and Management:

1.1 Construction Technology:

Engineering Materials:

Physical properties of construction materials with respect to their use in construction – Stones, Bricks and Tiles; Lime, Cement, different types of Mortars and Concrete.

Specific use of ferro cement, fibre reinforced C.C, High strength concrete.

Timber, properties and defects – common preservation treatments.

Use and selection of materials for specific use like Low Cost Housing, Mass Housing, High Rise Buildings.

1.2 Construction:

Masonry principles using Brick, stone, Blocks – construction detailing and strength characteristics.

Types of plastering, pointing, flooring, roofing and construction features.

Common repairs in buildings.

Principles of functional planning of building for residents and specific use – Building code provisions.

Basic principles of detailed and approximate estimating – specification writing and rate analysis – principles of valuation of real property.

Machinery for earthwork, concreting and their specific uses – Factors affecting selection of equipments – operating cost of Equipments.

1.3 Construction Planning and Management:

Construction activity – schedules- organization for construction industry – Quality assurance principles.

Use of Basic principles of network – analysis in form of CPM and PERT – their use in construction monitoring, Cost optimization and resource allocation.

Basic principles of Economic analysis and methods.

Project profitability – Basic principles of Boot approach to financial planning – simple toll fixation criterions.

2. Surveying and Transportation Engineering

2.1 Surveying:

Common methods and instruments for distance and angle measurement for CE work – their use in plane table, traverse survey, leveling work, triangulation, contouring and topographical map.

Basic principles of photogrammetry and remote sensing.

2.2 Railway Engineering:

Permanent way – components, types and their functions – Functions and Design constituents of turn and crossings – Necessity of geometric design of track – Design of station and yards.

2.3 Highway Engineering:

Principles of Highway alignments – classification and geometrical design elements and standards for Roads.

Pavement structure for flexible and rigid pavements – Design principles and methodology of pavements.

Typical construction methods and standards of materials for stabilized soil, WBM, Bituminous works and CC roads.

Surface and sub-surface drainage arrangements for roads – culvert structures.

Pavement distresses and strengthening by overlays.

Traffic surveys and their applications in traffic planning – Typical design features for channelized, intersection, rotary etc – signal designs – standard Traffic signs and markings.

3. Hydrology, Water Resources and Engineering:

3.1 Hydrology:

Hydrological cycle, precipitation, evaporation, transpiration, infiltration, overland flow, hydrograph, flood frequency analysis, flood routing through a reservoir, channel flow routing-Muskingam method.

3.2 Ground water flow:

Specific yield, storage coefficient, coefficient of permeability, confined and unconfined equifers, aquifers, aquitards, radial flow into a well under confined and unconfined conditions.

3.3 Water Resources Engineering:

Ground and surface water resource, single and multipurpose projects, storage capacity of reservoirs, reservoir losses, reservoir sedimentation.

3.4 Irrigation Engineering:

(i) Water requirements of crops: consumptive use, duty and delta, irrigation methods and their efficiencies.

(ii) Canals: Distribution systems for canal irrigation, canal capacity, canal losses, alignment of main and distributory canals, most efficient section, lined canals, their design, regime theory, critical shear stress, bed load.

(iii) Water logging: causes and control, salinity.

(iv) Canal structures: Design of, head regulators, canal falls, aqueducts, metering flumes and canal outlets.

(v) Diversion headwork: Principles and design of weirs of permeable and impermeable foundation, Khosla’s theory, energy dissipation.

(vi) Storage works: Types of dams, design, principles of rigid gravity, stability analysis.

(vii) Spillways: Spillway types, energy dissipation.

(viii) River training: Objectives of river training, methods of river training.

4. Environmental Engineering:

4.1 Water Supply:

Predicting demand for water, impurities, of water and their significance, physical, chemical and bacteriological analysis, waterborne diseases, standards for potable water.

4.2 Intake of water:

Water treatment: principles of coagulation, flocculation and sedimentation; slow-; rapid-, pressure-, filters; chlorination, softening, removal of taste, odour and salinity.

4.3 Sewerage systems:

Domestic and industrial wastes, storm sewage–separate and combined systems, flow through sewers, design of sewers.

4.4 Sewage characterization:

BOD, COD, solids, dissolved oxygen, nitrogen and TOC. Standards of disposal in normal watercourse and on land.

4.5 Sewage treatment:

Working principles, units, chambers, sedimentation tanks, trickling filters, oxidation ponds, activated sludge process, septic tank, disposal of sludge, recycling of wastewater.

4.6 Solid waste: Collection and disposal in rural and urban contexts, management of long-term ill effects.

5. Environmental pollution: Sustainable development. Rawastes and disposal. Environmental impact assessment for thermal power plants, mines, river valley projects. Air pollution. Pollution control acts

Civil Services Mains exam syllabus: Chemistry

Chemistry Syllabus for IAS Main Examination 2014

PAPER-I

1. Atomic Structure:

Heisenberg’s uncertainty principle, Schrodinger wave equation (time independent); Interpretation of wave function, particle in one-dimensional box, quantum numbers, hydrogen atom wave functions; Shapes of s, p and d orbitals.

2. Chemical Bonding:

Ionic bond, characteristics of ionic compounds, lattice energy, Born-Haber cycle; covalent bond and its general characteristics, polarities of bonds in molecules and their dipole moments; Valence bond theory, concept of resonance and resonance energy; Molecular orbital theory (LCAO method); bonding in H2+, H2, He2+ to Ne2, NO, CO, HF, and CN–; Comparison of valence bond and molecular orbital theories, bond order, bond strength and bond length.

3. Solid State:

Crystal systems; Designation of crystal faces, lattice structures and unit cell; Bragg’s law; X-ray diffraction by crystals; Close packing, radius ratio rules, calculation of some limiting radius ratio values; Structures of NaCl, ZnS, CsCl and CaF2; Stoichiometric and nonstoichiometric defects, impurity defects, semi-conductors.

4. The Gaseous State and Transport Phenomenon:

Equation of state for real gases, intermolecular interactions and critical phenomena and liquefaction of gases, Maxwell’s distribution of speeds, intermolecular collisions, collisions on the wall and effusion; Thermal conductivity and viscosity of ideal gases.

5. Liquid State:

Kelvin equation; Surface tension and surface energy, wetting and contact angle, interfacial tension and capillary action.

6. Thermodynamics:

Work, heat and internal energy; first law of thermodynamics.

Second law of thermodynamics; entropy as a state function, entropy changes in various processes, entropy–reversibility and irreversibility, Free energy functions; Thermodynamic equation of state; Maxwell relations; Temperature, volume and pressure dependence of U, H, A, G, Cp and Cv, ? and ?; J-T effect and inversion temperature; criteria for equilibrium, relation between equilibrium constant and thermodynamic quantities; Nernst heat theorem, introductory idea of third law of thermodynamics.

7. Phase Equilibria and Solutions:

Clausius-Clapeyron equation; phase diagram for a pure substance; phase equilibria in binary systems, partially miscible liquids–upper and lower critical solution temperatures; partial molar quantities, their significance and determination; excess thermodynamic functions and their determination.

8. Electrochemistry:

Debye-Huckel theory of strong electrolytes and Debye-Huckel limiting Law for various equilibrium and transport properties.

Galvanic cells, concentration cells; electrochemical series, measurement of e.m.f. of cells and its applications fuel cells and batteries.

Processes at electrodes; double layer at the interface; rate of charge transfer, current density; overpotential; electroanalytical techniques: Polarography, amperometry, ion selective electrodes and their uses.

9. Chemical Kinetics:

Differential and integral rate equations for zeroth, first, second and fractional order reactions; Rate equations involving reverse, parallel, consecutive and chain reactions; branching chain and explosions; effect of temperature and pressure on rate constant; Study of fast reactions by stop-flow and relaxation methods; Collisions and transition state theories.

10. Photochemistry:

Absorption of light; decay of excited state by different routes; photochemical reactions between hydrogen and halogens and their quantum yields.

11. Surface Phenomena and Catalysis:

Absorption from gases and solutions on solid adsorbents, Langmuir and B.E.T. adsorption isotherms; determination of surface area, characteristics and mechanism of reaction on heterogeneous catalysts.

12. Bio-inorganic Chemistry:

Metal ions in biological systems and their role in ion transport across the membranes (molecular mechanism), oxygen-uptake proteins, cytochromes and ferredoxins.

13. Coordination Compounds:

(i) Bonding theories of metal complexes; Valence bond theory, crystal field theory and its modifications; applications of theories in the explanation of magnetism and electronic spectra of metal complexes.

(ii) Isomerism in coordination compounds; IUPAC nomenclature of coordination compounds; stereochemistry of complexes with 4 and 6 coordination numbers; chelate effect and polynuclear complexes; trans effect and its theories; kinetics of substitution reactions in square-planer complexes; thermodynamic and kinetic stability of complexes.

(iii) EAN rule, Synthesis structure and reactivity of metal carbonyls; carboxylate anions, carbonyl hydrides and metal nitrosyl compounds.

(iv) Complexes with aromatic systems, synthesis, structure and bonding in metal olefin complexes, alkyne complexes and cyclopentadienyl complexes; coordinative unsaturation, oxidative addition reactions, insertion reactions, fluxional molecules and their characterization; Compounds with metal-metal bonds and metal atom clusters.

14. Main Group Chemistry:

Boranes, borazines, phosphazenes and cyclic phosphazene, silicates and silicones, Interhalogen compounds; Sulphur – nitrogen compounds, noble gas compounds.

15. General Chemistry of ‘f’ Block Elements: Lanthanides and actinides; separation, oxidation states, magnetic and spectral properties; lanthanide contraction.

Paper-II

1. Delocalised Covalent Bonding:

Aromaticity, anti-aromaticity; annulenes, azulenes, tropolones, fulvenes, sydnones.

2. (i) Reaction Mechanisms: General methods (both kinetic and non-kinetic) of study of mechanism of organic reactions: isotopic method, cross-over experiment, intermediate trapping, stereochemistry; energy of activation; thermodynamic control and kinetic control of reactions.

(ii) Reactive Intermediates: Generation, geometry, stability and reactions of carbonium ions and carbanions, free radicals, carbenes, benzynes and nitrenes.

(iii) Substitution Reactions: SN1, SN2 and SNi mechanisms; neighbouring group participation; electrophilic and nucleophilic reactions of aromatic compounds including heterocyclic compounds–pyrrole, furan, thiophene and indole.

(iv) Elimination Reactions: E1, E2 and E1cb mechanisms; orientation in E2 reactions–Saytzeff and Hoffmann; pyrolytic syn elimination – Chugaev and Cope eliminations.

(v) Addition Reactions: Electrophilic addition to C=C and C?C; nucleophilic addition to C=0, C?N, conjugated olefins and carbonyls.

(vi) Reactions and Rearrangements: (a) Pinacol-pinacolone, Hoffmann, Beckmann, Baeyer–Villiger, Favorskii, Fries, Claisen, Cope, Stevens and Wagner-Meerwein rearrangements.

(b) Aldol condensation, Claisen condensation, Dieckmann, Perkin, Knoevenagel, Witting, Clemmensen, Wolff-Kishner, Cannizzaro and von Richter reactions; Stobbe, benzoin and acyloin condensations; Fischer indole synthesis, Skraup synthesis, Bischler-Napieralski, Sandmeyer, Reimer-Tiemann and Reformatsky reactions.

3. Pericyclic Reactions: Classification and examples; Woodward-Hoffmann rules – electrocyclic reactions, cycloaddition reactions [2+2 and 4+2] and sigmatropic shifts [1, 3; 3, 3 and 1, 5] FMO approach.

4. (i) Preparation and Properties of Polymers: Organic polymers–polyethylene, polystyrene, polyvinyl chloride, teflon, nylon, terylene, synthetic and natural rubber.

(ii) Biopolymers: Structure of proteins, DNA and RNA.

5. Synthetic Uses of Reagents:

OsO4, HIO4, CrO3, Pb(OAc)4, SeO2, NBS, B2H6, Na-Liquid NH3, LiAlH4, NaBH4, n-BuLi and MCPBA.

6. Photochemistry:

Photochemical reactions of simple organic compounds, excited and ground states, singlet and triplet states, Norrish-Type I and Type II reactions.

7. Spectroscopy:

Principle and applications in structure elucidation:

(i) Rotational: Diatomic molecules; isotopic substitution and rotational constants.

(ii) Vibrational: Diatomic molecules, linear triatomic molecules, specific frequencies of functional groups in polyatomic molecules.

(iii) Electronic: Singlet and triplet states; n p* and p p* transitions; application to conjugated double bonds and conjugated carbonyls–Woodward-Fieser rules; Charge transfer spectra.

(iv) Nuclear Magnetic Resonance (1H NMR): Basic principle; chemical shift and spin-spin interaction and coupling constants.

(v) Mass Spectrometry: Parent peak, base peak, metastable peak, McLafferty rearrangement.

Civil Services Mains exam syllabus: Botany

Botany Syllabus for IAS Main Examination

PAPER-I

1. Microbiology and Plant Pathology: Structure and reproduction/multiplication of viruses, viroids, bacteria, fungi and mycoplasma; Applications of microbiology in agriculture, industry, medicine and in control of soil and water pollution; Prion and Prion hypothesis. Important crop diseases caused by viruses, bacteria, mycoplasma, fungi and nematodes; Modes of infection and dissemination; Molecular basis of infection and disease resistance/defence; Physiology of parasitism and control measures; Fungal toxins; Modelling and disease forecasting; Plant quarantine.

2. Cryptogams: Algae, fungi, lichens, bryophytes, pteridophytes – structure and reproduction from evolutionary viewpoint; Distribution of Cryptogams in India and their ecological and economic importance.

3. Phanerogams:

Gymnosperms: Concept of Progymnosperms; Classification and distribution of gymnosperms; Salient features of Cycadales, Ginkgoales, Coniferales and Gnetales, their structure and reproduction; General account of Cycadofilicales, Bennettitales and Cordaitales; Geological time scale; Type of fossils and their study techniques.

Angiosperms: Systematics, anatomy, embryology, palynology and phylogeny.

Taxonomic hierarchy; International Code of Botanical Nomenclature; Numerical taxonomy and chemotaxonomy; Evidence from anatomy, embryology and palynology.

Origin and evolution of angiosperms; Comparative account of various systems of classification of angiosperms; Study of angiospermic families – Mangnoliaceae, Ranunculaceae, Brassicaceae, Rosaceae, Fabaceae, Euphorbiaceae, Malvaceae, Dipterocarpaceae, Apiaceae, Asclepiadaceae, Verbenaceae, Solanaceae, Rubiaceae, Cucurbitaceae, Asteraceae, Poaceae, Arecaceae, Liliaceae, Musaceae and Orchidaceae.

Stomata and their types; Glandular and non-glandular trichomes; Unusual secondary growth; Anatomy of C3 and C4 plants; Xylem and phloem differentiation; Wood anatomy.

Development of male and female gametophytes, pollination, fertilization; Endosperm – its development and function; Patterns of embryo development; Polyembroyony and apomixes; Applications of palynology; Experimental embryology including pollen storage and test-tube fertilization.

4. Plant Resource Development: Domestication and introduction of plants; Origin of cultivated plants; Vavilov’s centres of origin; Plants as sources for food, fodder, fibre, spices, beverages, edible oils, drugs, narcotics, insecticides, timber, gums, resins and dyes, latex, cellulose, starch and its products; Perfumery; Importance of Ethnobotany in Indian context; Energy plantations; Botanical Gardens and Herbaria.

5. Morphogenesis: Totipotency, polarity, symmetry and dfferentiation; Cell, tissue, organ and protoplast culture; Somatic hybrids and Cybrids; Micropropagation; Somaclonal variation and its applications; Pollen haploids, embryo rescue methods and their applications.

PAPER-II

1. Cell Biology:

Techniques of cell biology; Prokaryotic and eukaryotic cells – structural and ultrastructural details; Structure and function of extracellular matrix (cell wall), membranes-cell adhesion, membrane transport and vesicular transport; Structure and function of cell organelles (chloroplasts, mitochondria, ER, dictyosomes ribosomes, endosomes, lysosomes, peroxisomes); Cytoskelaton and microtubules; Nucleus, nucleolus, nuclear pore complex; Chromatin and nucleosome; Cell signalling and cell receptors; Signal transduction; Mitosis and meiosis; Molecular basis of cell cycle; Numerical and structural variations in chromosomes and their significance; Chromatin organization and packaging of genome; Polytene chromosomes; B-chromosomes – structure, behaviour and significance.

2. Genetics, Molecular Biology and Evolution:

Development of genetics; Gene versus allele concepts (Pseudoalleles); Quantitative genetics and multiple factors; Incomplete dominance, polygenic inheritance, multiple alleles; Linkage and crossing over; Methods of gene mapping, including molecular maps (idea of mapping function); Sex chromosomes and sex-linked inheritance, sex determination and molecular basis of sex differentiation; Mutations (biochemical and molecular basis); Cytoplasmic inheritance and cytoplasmic genes (including genetics of male sterility).

Structure and synthesis of nucleic acids and proteins;Genetic code and regulation of gene expression; Gene silencing; Multigene families; Organic evolution – evidences, mechanism and theories. Role of RNA in origin and evolution.

3. Plant Breeding, Biotechnology and Biostatistics:

Methods of plant breeding – introduction, selection and hybridization (pedigree, backcross, mass selection, bulk method); Mutation, polyploidy, male sterility and heterosis breeding; Use of apomixes in plant breeding; DNA sequencing; Genetic engineering – methods of transfer of genes; Transgenic crops and biosafety aspects; Development and use of molecular markers in plant breeding; Tools and techniques – probe, southern blotting, DNA fingerprinting, PCR and FISH.

Standard deviation and coefficient of variation (CV); Tests of significance (Z-test, t-test and chi-square test); Probability and distributions (normal, binomial and Poisson); Correlation and regression.

4. Physiology and Biochemistry:

Water relations, mineral nutrition and ion transport, mineral deficiencies; Photosynthesis – photochemical reactions; photophosphorylation and carbon fixation pathways; C3, C4 and CAM pathways; Mechanism of phloem transport; Respiration (anerobic and aerobic, including fermentation) – electron transport chain and oxidative phosphorylation; Photorespiration; Chemiosmotic theory and ATP synthesis; Lipid metabolism; Nitrogen fixation and nitrogen metabolism; Enzymes, coenzymes; Energy transfer and energy conservation; Importance of secondary metabolites; Pigments as photoreceptors (plastidial pigments and phytochrome); Plant movements; Photoperiodism and flowering, vernalization, senescence; Growth substances – their chemical nature, role and applications in agri-horticulture; Growth indices, growth movements; Stress physiology (heat, water, salinity, metal); Fruit and seed physiology; Dormancy, storage and germination of seed; Fruit ripening – its molecular basis and manipulation.

5. Ecology and Plant Geography:

Concept of ecosystem; Ecological factors; Concepts and dynamics of community; Plant succession; Concept of biosphere; Ecosystems; Conservation; Pollution and its control (including phytoremediation); Plant indicators; Environment (Protection) Act.

Forest types of India – Ecological and economic importance of forests, afforestation, deforestation and social forestry; Endangered plants, endemism, IUCN categories, Red Data Books; Biodiversity and its conservation; Protected Area Network; Convention on Biological Diversity; Farmers’ Rights and Intellectual Property Rights; Concept of Sustainable Development; Biogeochemical cycles; Global warming and climatic change; Invasive species; Environmental Impact Assessment; Phytogeographical regions of India.